By D. H. Collins
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Extra info for Batteries 2. Research and Development in Non-Mechanical Electrical Power Sources
BODE, H . and Voss, E. Electrochim. Acta, 1, 318 (1959). 4. , SKLARCHUK, J. and ANGSTADT, R . T . Batteries, Research and Development in Non-Mechanical Power Sources, p . 89. Collins D . H . , Pergamon Press, London, 1963. 5. CREIGHTON, H . J. Principles and Applications of Electrochemistry 4th Ed. V o l . I. Wiley, New York, 1943. 6. VINAL, G . W . Storage Batteries, Wiley, New York, 1956. 7. GREENBURG, R . H . , FINAN, F. B. and AGRUSS, B. J. Electrochem. Soc. 9 8 , 474 (1951). 8. (a) W I L L , F.
Therefore any material in this region which is formed before equilibration o f p H has been achieved is converted under conditions o f relatively high p H , and hence below the potentials required for the decomposition o f water. It is therefore possible that the efficiency o f formation is greater during the early stages o f the process than it is during the later stages. T h e nature o f the product formed when lead and divalent lead compounds are oxidized has been shown to be dependent upon the p H in the vicinity o f the reaction interface.
It is a difficult thing to measure quantitatively but banging the grid on a bench or dropping it on the floor is sufficient to enable an assessment to be made. A. HOVENKAMP (Technical University, Delft, Holland) : 1. Gould you inform me how you determined the lead concentration? 2. (Page 5). What positive ions are present in the negative paste? 3. In a positive paste with P b 0 you conclude that each particle is surrounded by a layer of tribasic sulphate. This would involve the formation of either P b O or oxygen.
Batteries 2. Research and Development in Non-Mechanical Electrical Power Sources by D. H. Collins